Category Archive: Blogs

Why Should I Use Tantalum in Corrosive Environments?

Refractory metals are metallic elements that exhibit properties that make them more durable than other metals. For example, they can demonstrate corrosion resistance, thermal and electrical conductivity, and deformation resistance. These characteristics make them ideal for use in highly demanding applications and environments. One example of refractory metals is tantalum, which is prized for its excellent resistance to corrosion. 

What Is Tantalum?

Tantalum is among the most corrosion-resistant of the refractory metals. It possesses a protective oxide layer that is extremely difficult to remove, even when it is exposed to strong and hot acid environments. This layer results in a material with a non-detectable corrosion rate, which essentially means it cannot corrode. For this reason, it is commonly used in the fabrication of the following components:  

Heat Exchanger and Column, Heat Exchanger Gas separation plant, power plant.

  • Columns
  • Condensers
  • Heat exchangers
  • Helical coils
  • Pipe Stools
  • Reactors
  • Valve linings

Tantalum in Highly Corrosive Environments

Due to its unique characteristics, tantalum is ideal for parts and products used in highly corrosive environments. Its resistance to corrosion and inertness with most acids enable it to withstand long-term use within them. Since it is not damaged or degraded by acids, it can remain in contact with the media for extended periods. 

The material is often used for equipment for the chemical processing and pharmaceutical industries since they generally involve hot and highly corrosive environments. It can stand up to exposure to hot, concentrated acids, like hydrochloric acid (HCI) or sulfuric acid (H2SO4). Other industries that use it include aerospace, electronics, medical, steel finishing, and tooling.

Tantalum Products From ADMAT

Tantalum is an ideal material choice for applications where long-term corrosion resistance is critical. If you’re looking for a reliable supplier of tantalum products, ADMAT has got you covered. We’ve provided refractory metals, including tantalum, in various forms for over 20 years. This vast experience has allowed us to fully understand the importance and benefits of specialty materials, which is why we are committed to providing our customers the highest quality products. They find use in a range of industrial applications since they are compliant with many industry standards.

We offer the following tantalum products

tantalum rod

  • Sheet/plate
  • Rod
  • Bar
  • Wire
  • Tube
  • Strip
  • Foil
  • Sinter bar
  • Powder
  • Oxide
  • Grain stabilized
  • Sputtering target
  • Spring wire

To learn more about tantalum in general or our tantalum products, contact us today. For specific product or pricing details, request a quote.

Learn More About Our Tantalum Products

The Characteristics and Manufacturing Process of Tantalum and Niobium

Tantalum and niobium are transition metals that are commonly found together in nature. They are often difficult to separate from one another due to their similarities in physical and chemical characteristics. In fact, when tantalum was first discovered in 1802, it was confused with niobium, which was discovered much earlier in 1734. It was not recognized as a separate element until 1864. 

While the two materials have many shared properties, there are some key differences between them. Below we highlight each material’s unique characteristics and manufacturing process.

The Characteristics and Manufacturing Process of Tantalum

Tantalum is a dark blue-gray metal that is hard, dense, and ductile. It is also easily fabricated, highly conductive to electricity and heat, and exceptionally resistant to corrosion.

  1. Separation: Since tantalum is often found with niobium, it must undergo a separation process before it can be further refined and used. This process involves treating the ore with a mixture of hydrofluoric acid and sulfuric acid at elevated temperatures, which dissolves the tantalum and niobium into complex fluorides.
  2. Purification: Since other elements are generally present within the ore, the slurry is first filtered and then further processed using a solvent extraction process that uses methyl isobutyl ketone or a liquid ion exchange process that uses an amine extractant in kerosene. The result is a highly purified solution of tantalum.
  3. Conversion: The purified tantalum solution can be turned into tantalum oxide (Ta2O5) or potassium tantalum fluoride (K2TaF7) as needed.
  4. Metal Production: The final step is to convert the tantalum compound into pure tantalum metal using an electrolytic or chemical reduction process.

The Characteristics and Manufacturing Process of Niobium

Niobium—initially known as columbium—is a lustrous gray metal with a high melting point and low density. It is highly ductile and superconductive. 

There are two main processes used for niobium production. They are utilized depending on whether pyrochlore or columbite and tantalum-bearing ores are being processed. 

99.95% fine niobium isolated on white background

  • Pyrochlore Ores: These ores undergo a process that converts the niobium oxide into HSLA ferroniobium. The conversion is performed either through an aluminothermic reduction process or by reduction in an electric arc furnace.
  • Columbite and Tantalum-bearing Ores: These ores undergo the same chemical process outlined in the Tantalum section. Typically, ammonia is introduced to the purified solution of niobium to convert it into niobium hydroxide. The resulting compound is then washed, filtered, and calcined.
  • Metal Production: The calcined niobium hydroxide is then reduced to pure niobium metal using an electrolytic or chemical reduction process.

Learn More About Tantalum and Niobium From the Experts at ADMAT

Want to learn more about tantalum and niobium? Ask the experts at ADMAT! As a leading supplier of refractory metals, including tantalum and niobium, they can answer and address any questions or concerns you may have about these materials. If you want to purchase these metals for your next project, request a quote.

Learn More About Our Tantalum Products

Learn More About Our Niobium Products

Choose the Right Tantalum Rod for your Application

Tantalum Rods From Admat Inc.

If you need a metal rod that can withstand high temperatures and has extremely strong chemical resistance to most corrosive environments then tantalum rod is already on your short list of materials.

Tantalum belongs to a class of metals known as refractory metals, which are defined by their strong resistance to heat and wear. It has a melting point of 5,463 °F (2,996 °C), the fourth highest of all metals.  Like most metals, tantalum forms a thin but dense protective oxide layer (Ta2O5) when exposed to the atmosphere. This oxide layer firmly adheres to the surface of the metal, acting as a barrier which protects the underlying metal from further corrosion.

More information on the general properties of tantalum rod can be found on Admat’s Tantalum Properties Page or Admat’s Tantalum Rod Product Page.

 

Below are some examples of common applications for tantalum rods.  Included with each application are some suggestions based on how others in that industry specify the tantalum rods for such uses.  If your application is not on the list, we suggest contacting Admat’s technical sales at 484-322-2091.

 

Machined fasteners

Machined tantalum fasteners are bolts, screws, nuts, washers and threaded rods which are fabricated from tantalum metal rods.  They replace fasteners made of alternative materials prone to failure or that require expensive equipment shutdowns for maintenance. Tantalum fasteners appear in industries such as mining, energy, and pharmaceuticals as well as in metal and chemical processing.  For customers who prefer to make their own fasteners unannealed tantalum rod is most commonly requested.  Annealed tantalum rods are sometimes  difficult to machine because the metal has a tendency to gum.  Unannealed tantalum rods make machining and threading easier.  As a service to our customers, Admat also offers machined fasteners to your custom sizes

Vacuum furnace heating elements  Because of tantalum’s oxidation resistance and high melting point, many vacuum furnace components incorporate tantalum rods. Grain stabilized tantalum rod is designed to survive longer in high temperature environments by reducing grain growth.  Admat can grain stabilize tantalum rods by producing the product using a powder metallurgy process which creates a very uniform and fine grain size or as an alternative the rods can be produced with very small amounts of additives such a Yttrium.  Either method prolongs or prevents the tantalum grains from growing and therefore increases machine life expectancy due to its ability to withstand high temperatures for long periods of time.

Machined parts for chemical processing equipment Tantalum rods have corrosion-resistant properties which make it a choice material for machined parts used in chemical processing equipment. Tantalum machined parts replace inferior materials that do not perform as well in harsh chemical environments and require extensive maintenance.  In most cases customer request tantalum 2.5% tungsten rod which has slightly more strength and corrosion resistance.  When ordering tantalum rods for such applications we suggest you order to ASTM B365 R05200 for pure tantalum rods or ASTM B365 R05252 for tantalum 2.5% tungsten rods.

X-ray/radiation shielding – Due to its high density, tantalum’s radio-opaque qualities make it ideal for X-ray and shielding applications seeking to prevent radiation leakage. Tantalum rods are often manufactured into shielding which protect sensitive electronic components in aerospace structures as well as components operating in corrosive environments.  There is great variability in the tantalum rods used in applications such as this.  Because the shielding is due to tantalum’s density, which is intrinsic, just about any grade of tantalum rod will be functional.

Sputtering Targets for Gun Barrels – Tantalum rods are sometimes used as a sputtering target to coat the inside of gun barrels with tantalum as a replacement for chromium.  This makes the gun barrel manufacturing process more environmentally friendly and lets manufacturers reduce their ecological impact.  When purchasing tantalum for such an application most customers prefer tantalum rods that are fully annealed, melted in an electron beam furnace (ASTM B365 R05200) and have a 99.95% minimum purity.  Some customers have specified tantalum 2.5% tungsten or tantalum 10% tungsten rods.

Learn More About Our Tantalum Rod Products

Facts about Tantalum

Tantalum (Ta) is an unsung hero in modern metallurgy. First discovered by the Swedish chemist Anders Ekeberg in 1802, this versatile metal has become essential to numerous industries over the years.

Raw tantalum rarely occurs in nature. Instead, it is typically found in the ore columbite-tantalite (usually referred to as coltan). Once extracted, pure tantalum is a hard blue-gray lustrous metal.

Since its discovery, tantalum has been used in a number of applications. In the 21st century, it has become a crucial element in the electronics industry, with over 75% of electronics containing tantalum in some form. In particular, engineers have been able to take advantage of some of tantalum’s properties to make capacitors and other components smaller and more efficient.

Properties of Tantalum

Tantalum has several unique characteristics that have led to its increased use in the 21st century. It is a highly stable metal that is almost immune to chemical degradation at temperatures lower than 302 °F (159 °C). In addition, it exhibits high levels of corrosion resistance when it comes into contact with air and moisture.

Like most metals, tantalum forms a thin but dense protective oxide layer (Ta2O5) when exposed to the atmosphere. This oxide layer firmly adheres to the surface of the metal, acting as a barrier which protects the underlying metal from further corrosion.

Tantalum belongs to a class of metals known as refractory metals, which are defined by their strong resistance to heat and wear. It has a melting point of 5,463 °F (2,996 °C), the fourth highest of all metals.

In terms of mechanical properties, tantalum is highly ductile, making it suitable for processes such as bending, stamping, and pressing. When combined with other metals, it can produce alloys with enhanced strength and higher melting points.

Common Uses of Tantalum

Tantalum is generally used in applications that require increased heat, corrosion, and chemical resistance. Below is a list of the commonly available forms of tantalum and their most common uses.

  • Sheet/Plate – Tantalum’s high melting point makes it ideal for high-temperature applications. In sheet form, it is commonly used in linings for columns, vessels, tanks, heat exchangers, and vacuum furnace parts. Thin sheets can also be used for anti-corrosion cladding, repairs, and reinforcement of existing
  • Rod/Wire – Tantalum is also known for its biocompatibility. In other words, it is a nonirritating element that is not affected by bodily fluids. This property makes tantalum wires a popular material for prosthetic implants and other medical devices. In addition, tantalum wires are commonly used in vacuum furnace heating elements, chlorinator springs, light bulb elements, and chemical processing equipment.
  • Powder – In its powder form, tantalum is used to produce electrical circuits, capacitors, and resistors, primarily because its superior capacitance allows it to hold more charge per gram than other materials. This has made it possible to develop smaller electrical parts and, by extension, smaller electrical devices.
  • Tube – Because of their heightened resistance to corrosion, tantalum tubes are often employed in the chemical, petrochemical, and pharmaceutical industries for the processing of compounds that may weaken or destroy other metals. Columns, stacks, and piping are just some of the products constructed from tantalum tubing in these industries.
  • Strips and foils – Similar to sheets, tantalum strips and foils can be used as liners in vacuum furnaces and heat insulation applications. Thin-gauge tantalum strips can also be deep drawn to manufacture crucibles, cups, and other inert laboratory equipment.

Tantalum Physical & General Properties

  • Element Category – Transition Metals
  • Phase – Solid
  • Symbol – Ta
  • Number – 73
  • STD Atomic Weight – 180.94788
  • Crystal Structure – Body Centered Cubic
  • Melting Temperature – 5463° F, 3017° C, 3290 K
  • Boiling Temperature – 9856° F, 5458° C, 5731 K
  • Electrical Resistivity – 20° C, 131 nΩ·m
  • Thermal Conductivity – 300 K, 57.5 W·m−1·K−1
  • Thermal Expansion – 25°C, 6.3 µm·m−1·K−1

Standard Specifications

  • Tantalum Ingot – ASTM B364
  • Tantalum Rod and Wire – ASTM B365
  • Tantalum Tubing – ASTM B521
  • Tantalum Sheet, Plate, Strip and Foil – ASTM B708
  • Medical Grade Tantalum – ASTM F560

Common Tantalum Alloys (UNS Codes)

  • Unalloyed Tantalum (EB Melted) – R005200
  • Unalloyed Tantalum (Powder Metallurgy Grade) – R05400
  • Tantalum 2.5% Tungsten – R05252
  • Tantalum 10% Tungsten – R05255
  • Tantalum 7.5% Tungsten – Spring Grade
  • Grain Stabilized – Furnace Grain

Commercial Grade ASTM Tantalum Purities

  • 99.5% Pure 3N5
  • 99.9% Pure 4N
  • 99.995% Pure 4N5
  • 99.999% Pure 5N

If you’re interested in discussing how tantalum can be used for your application, please feel free to contact our technical team directly.

Learn More About Our Tantalum Products

Tantalum Prices are Climbing… So What Can You Do About It?

If you buy tantalum, you have surely noticed that tantalum prices are climbing. That’s because demand for the versatile gray metal is quickly escalating. The latest forecasts from industry leaders predict a 4-7 year increase in demand and higher market prices for the ore, capacitor powder, melt stock and mill products.

As smartphone and electronics usage grows in third world nations, an increased requirement of tantalum capacitors will drive powder sales. Turbine engine demand in the Asian-Pacific region will require significant volumes of tantalum for their nickel based super-alloys. These factors combined with growth in the chemical processing, defense and semiconductor markets will likely sustain high tantalum demand and continue to drive ore prices.

Some large tantalum users have already begun protecting themselves by entering into blanket contracts for as long as 24 months. These agreements allow suppliers such as Admat to purchase the raw materials at today’s market price. Finished goods are still shipped and invoiced when the customers releases them.

Another method to cut costs is by shifting the machining or fabrication steps to the tantalum supplier. By reducing product weight by purchasing lighter finished or nearly finished parts a substantial savings could be realized. Tantalum suppliers usually have efficient recycle systems in place which means the turnings or trimmings have a higher scrap value as compared to selling the material to traders yourself.

There is really no way to avoid the higher market prices of tantalum over the next few years, but by taking a few extra steps and working with your supplier, there is the opportunity of putting your business in a better position than the competition. If your business is interested in exploring what options are available to limit your exposure to the higher prices, now is the time to contact your supplier. To discuss your options with Admat, please call 484-322-2091.

Learn More About Our Tantalum Products

Save Money by Improving Tantalum Yields

Let’s face it, if you’re buying tantalum, it’s probably because you have no choice. Your application likely demands one of the robust characteristics of the metal, such as the unmatched corrosion resistance, or the magnetic shielding properties, or maybe it’s the extremely high melting temperature. Regardless of why you need it, tantalum is always expensive when compared to metals such as steel, copper or even titanium.

One of the simplest ways to cut tantalum expenses is to improve your yields and reduce the amount of scrap you generate.

  • Why order material in typical rectangular sheet sizes and cut circles out yourself?
  • Why order plates oversized so you can machine to tolerances yourself?
  • Why machine parts from square bricks when you can order near finished custom shapes?

Admat specializes in custom shapes and sizes. Whether it’s round, oval, or an octagon with a square hole, Admat can machine or cut to your requirements. Because the scrap is kept internal to the manufacturing plant, it maintains a higher value and therefore saves you money. Tight tolerances are nothing new to Admat. We will review your requirements and quote you a price on a product that we stand behind.

Speak with our sales department today and find out how Admat can improve your tantalum yields.

Learn More About Our Tantalum Products

Hafnium – It’s Elemental

Hafnium is element 72 on the periodic table. It is a tetravalent transition metal colored silver gray and is often found in zirconium, its sister element. Discovered in 1923 in Copenhagen, it was named after the city’s Latin name, Hafnia.

Hafnium is used in many industries and hi-tech applications. Some of these include: coatings of nuclear materials in power plants, alloying agents in superalloys, coatings on cutting tools and optics, and in the production of semiconductors. Current demand for Hafnium is just 75 to 80 tons a year. Primary sources for Hf raw materials come from Australia, South America, and China. Supply of the material is estimated at 67 to 72 tons per year. A portion of the superalloy demand is fulfilled with scrap and recycled material.

The largest market for hafnium is the superalloy industry. It is estimated that about 55% of demand comes from producers of alloys which are most commonly used in turbine blades for either aircraft engines or land based turbines in power plants. Because engineers are always seeking new space age materials to improve performance, hafnium is expected to see significant growth in this industry. The metal has been shown to allow aircraft engines to run hotter while being safer and using less fuel. Additionally alloys such as C-103*, a Nb-Hf-Ti alloy is commonly used to make rocket nozzles as it stands up to high temperatures and corrosive chemicals.

Another 15% of Hf demand comes from nuclear power plants which use Hf to coat their nuclear fuel. Because the material is able to absorb neutrons, it is ideal for such applications. There are a significant number of nuclear power plants throughout the world, and that number is ever increasing. Hf demand will be strong for this market as the power plants will utilize the material in both the nuclear reactor and the power generating turbine blades used to create electricity. Constant maintenance of these plants will assure the demand for years to come.

There are smaller applications as well. Roughly 8% of demand is for hafnium welding tips for use with plasma torches. Because Hf sheds electrons and can create an arc, it is an ideal material to use in place of tungsten.

Together, demand for hafnium chloride (HfCl4), hafniumoxide> ( HfO2)and pure hafnium for chemical vapor deposition (CVD) and physical vapor deposition (PVD) totals about 22% of the material demand. This accounts for a combination of end uses which include hard and protective coatings on cutting tools and optics, blue lasers for use in DVD players, and high-k dielectrics, where Hf is ideal to improve the miniaturization and reliability of electronic components.

For most electronic applications hafnium with .2 to .5 percent zirconium is used effectively. For select applications customers may require hafnium with less than .1 percent zirconium content. This grade is priced at a premium because of the difficulty and high cost to produce such high purity Hf.

If your business is seeking a reliable partner for the supply of high purity Hf target plates and discs, contact Admat Inc. (www.admatinc.com), a stocking supplier of electronic grade hafnium targets.

*C-103 is a trademark of Allegheny Technologies Inc.

Why You Should Not Buy Tantalum from an Inexperienced Reseller

 

When you call your local metal supplier and ask for a coil of tantalum sheet or a plate of niobium, do they ask you about your application? Do they ask you what type of machining you will be performing or if you’re drawing parts from this material? These are examples of important questions to ask.

If you’re a new customer to Admat, we always ask these questions. Not to be nosy or to take up your time. But, because tantalum and niobium are unique metals which can be manufactured in multiple fashions. After all tantalum and niobium are expensive and we don’t want to sell you something that will not work in your application. For example, a customer using material for stamped parts will want softer metal that is able to be drawn without the surface becoming grainy or tearing, while someone using the material for shielding may want the material stiffer. Some customers use the material for semiconductors and they want exceptional purity of 99.999% pure while others are lining a chemical tank and 98% pure is less expensive and ideal for their job.

We can supply material in multiple tempers, with “as rolled” surfaces, or conditioned surfaces. Admat’s extensive experience with these metals can help you decipher what your material requirements should be, in most cases, just by asking a few questions. Still it is always a good idea to get a basic understanding of the typical standards yourself.

There are so many different specifications of tantalum that one can easily become confused. It’s important to be educated regarding specifications and grades of tantalum and how they apply to the materials.

Learn More About Our Tantalum Products

Admat Inc. Adds Fabricated and Machined Refractory Metal Parts to Product List

Admat Incorporated of Norristown, PA has further enhanced their product portfolio to include machined and fabricated parts. Since 1997, Admat has been supplying Tantalum powders and mill products to a variety of industries.

Over the years, Admat has become one of the largest sources of refractory metals in the US. Now they have partnered with a number of skilled and specialized fabricators to offer custom machined parts.

Admat’s management team has the most experience in development, engineering, sales and services in the refractory metal industry. Through the years their team has developed powders for specialty alloys and 3D printing, precision wire products for medical implants, penetrators for missile systems, explosively bonded metals for corrosion prevention, and cutting edge products for semiconductor production, just to name a few.

Eric von Spreckelsen, Admat’s Director of Sales and Operations stated, “All this experience has given Admat a portfolio that is unmatched. No matter what you require, a tube, a rod, a plate or a complex fabricated part, we are the best place to call.” Metals include tantalum, niobium, tungsten, molybdenum and titanium. Their technical know-how allows them to precisely and efficiently manage the raw material production and the subsequent fabrication operations to provide customers the highest quality product in the market today at very competitive prices.

Allen Chang is Admat’s Engineering Manager. Over the past three years he has developed systems and procedures to ensure 100% compliance to specification. Allen directly oversees all fabrication and machining operations and is an asset to the machined parts business at Admat.

Whether your business needs tantalum flanges, molybdenum crucibles, electron beam welded assemblies, threaded rods, or tungsten machined parts, Admat should be your first call. Contact us today!

Learn More About Our Tantalum Fabrication and Machining Suggestions

The Value of Tantalum Experience

Tantalum is expensive. For most users of Tantalum, it is likely the most expensive material they buy. It’s for that reason that so many companies source their material from smaller mills overseas to avoid paying the higher prices charged by the big American mills. But with so many companies selling tantalum, how can you tell a reputable company from a fly by night re-seller? Is there a way to ensure they are producing product using the best metallurgy practices? And how can you be sure these companies will stand behind their products when something goes awry? To be perfectly honest, you can’t really be sure of these things without performing significant due diligence such as costly plant audits, independent third party testing, detailed engineering studies and utilizing years of experience. That’s what Admat brings to the table.

Admat’s management team has 50 years of tantalum experience, more than anyone else in the industry. What makes that knowledge so valuable is that it’s a blend of domestic sales and manufacturing know-how combined with years of overseas production and engineering expertise. This gives us the unique ability to understand the culture of both our customers and our factories.

We understand your application and what material properties are important to you. Our engineers can adapt production techniques to produce product that is engineered specifically for your application. Whether it is high purity plates with fine grain for semiconductor production, grain stabilized rods for vacuum furnace parts, or isotropic strip for stamped parts, Admat has the experience and know how to help your business.

We have multiple contracted production plants throughout Asia. Each of these plants has undergone multiple on site audits and their range of products have undergone studies which include testing at independent labs. Each plant’s production process is unique and therefore each has specific strengths and weakness. For example, some plants melt large diameter ingots that are rolled down directly to finished product, where others use small diameter ingots which require upset forging prior to rolling.

 

This photo shows grain flow in tantalum rods. Although on the outside, both rods would look identical to anyone, the metallurgy on the inside is completely different. Depending on your application, this could completely change how the material performs. Matching your unique material requirements with the right production method is an example of the value that Admat’s experience provides our customers.

Since 1997, Admat’s customers have come to expect a high level of quality and service. It is our goal to provide your company with the highest quality products available and to do so at a price that makes your business more competitive in the marketplace.

Call us today and let us show you how Admat can strengthen your raw materials position. Contact us for more information